Acesulfame potassium impurity B is a degradation byproduct arising from the hydrolytic cleavage of the sulfonamide moiety in the parent acesulfame structure. It retains the 6-methyl-1,2,3-oxathiazole core but features a sulfinic acid functional group in place of the terminal amide, resulting in reduced thermal stability. This impurity forms under acidic conditions during synthesis or storage, reflecting a partial oxidation pathway. It serves as a critical HPLC reference standard for quantifying degradation in acesulfame formulations.
On RequestCC1=C(C(=O)NS(=O)(=O)O1)Cl
InChI=1S/C4H4ClNO4S/c1-2-3(5)4(7)6-11(8,9)10-2/h1H3,(H,6,7)
YVZOKLTZSNJEQX-UHFFFAOYSA-N