Mometasone Furoate - Impurity A is a synthetic byproduct arising from the oxidation of the parent corticosteroid's furan-2-ylcarbonyl moiety, resulting in a chlorinated cyclohexyl substitution at the C25 position. This impurity retains the core 11ฮฒ,17ฮฑ-dihydroxy-17ฮฒ-carboxylic acid ester scaffold but features an altered side chain configuration, leading to reduced glucocorticoid receptor affinity. It serves as a critical HPLC reference standard for quantifying process-related variability in API synthesis.
On RequestC[C@@H]1C[C@H]2[C@@H]3CCC4=CC(=O)C=C[C@@]4(C3=CC[C@@]2([C@]1(C(=O)CCl)OC(=O)C5=CC=CO5)C)C
InChI=1S/C27H29ClO5/c1-16-13-21-19-7-6-17-14-18(29)8-10-25(17,2)20(19)9-11-26(21,3)27(16,23(30)15-28)33-24(31)22-5-4-12-32-22/h4-5,8-10,12,14,16,19,21H,6-7,11,13,15H2,1-3H3/t16-,19-,21+,25+,26+,27+/m1/s1
GSJLBVBYMSNTPZ-XACSLSAESA-N